Copper Datas in eV
8979 1.55 1096.7 3.06 952.3 0.62 932.7 0.56 8047.78 2.11a / 3.20b 8027.83 2.17a / 3.83b 8905.29

Main beamline parameters at K-edge
Bending Magnet Monochromator Mirrors
Vertical div. (mrad) Cristal type Angle (°) Resolution (eV) Angle (mrad) Cut-off energy (keV)
0.187 Si(220) 21.10 0.460 4.3 13.5
Si(111) 12.74 1.23

Main crystal analyzer spectrometer parameters at K-edge
Line Crystal
Name E (eV) Type Bragg angle (°)
EKα1 8047.78 Si(444) 79.330
EKß1 8905.29








Experiments already done with this element / available references

Earth & Environmental Sciences

Collin B., Doelsch E., Keller C., Cazevieille P., Tella M., Chaurand P., Panfili F., Hazeman J-L., Meunier J.-D. “Copper distribution and speciation in bamboo exposed to a high Cu concentration and Si supplementation. First evidence on the presence of reduced copper bound to sulfur compounds in Poaceae”, Environmental Pollution 187 (2014) 22-30

Manceau A., Simionovici A., Lanson M., Perrin J., Tucoulou R., Bohic S., Fakra S. C., Marcus M., Bedell J.P., Nagy K., “Thlaspi arvense binds Cu(II) as a bis-(L-histidinato) complex on root cell walls in an urban ecosystem”, Metallomics 5 (2013) 1674-1684

Schlegel M.L., Manceau A., “Binding mechanism of Cu(II) at the clay-water interface by powder and polarized EXAFS spectroscopy”, Geochimica et Cosmochimica Acta 113 (2013) 113-124

Pokrovsky O.S., Pokrovski G.S., Shirokova L.S., Gonzalez A.G., Emnova E.E., Feurtet-Mazel A., “Chemical and structural status of copper associated with oxygenic and anoxygenic phototrophs and heterotrophs: possible evolutionary consequences”, Geobiology 10 (2012) 130-149

Etschmann B., Liu W., Testemale D. Müller H., Proux O., Hazemann J.-L., Brugger J., “An in situ XAS study of copper transport in hydrothermal sulfuric solutions (25 °C to 600 °C, 600 to 180 bar): speciation and partitioning between vapor and liquid phases”, Geochimica et Cosmochimica Acta 74 (2010) 4723-4739

Manceau A., Matynia A., “The Nature of Cu Bonding to Natural Organic Matter”, Geochimica Cosmochimica Acta 74 (2010) 2556–2580

Liu W., Brugger J., Etschmann B., Testemale D., Hazemann J.-L., “The solubility of nantokite (CuCl(s)) and Cu speciation in low density fluids near the critical isochore: an in-situ XAS study”, Geochimica et Cosmochimica Acta 72 (2008) 4094–4106

Manceau A., Nagy K.L., Marcus M.A., Lanson M., Geoffroy N., Jacquet T., Kirpichtchikova T. “Formation of metallic copper nanoparticles at the soil-root interface”, Environmental Science & Technology 42 (2008) 1766-1772

Brugger J., Etschmann B., Liu W., Testemale D., Hazemann J.-L., Emerich H., van Beek W., Proux O., C. Tran, “An XAS study of the structure and thermodynamics of Cu(I) chloride complexes in brines up to high temperature (400°C, 600 bars)”, Geochimica et Cosmochimica Acta 71 (2007) 4920–4941

Chemistry, Catalysis & Electrochemistry

Soldo Y., E. Sibert, G. Tourillon, J.L. Hazemann, J.P. Levy, D. Aberdam, R. Faure, R. Durand, "In situ X-ray absorption spectroscopy study of copper under potential deposition on Pt(111): role of the anions on the Cu structural arrangement", Electrochimica Acta 47 (2002) 3081-3091


Jullien A.-S., Gateau C., Lebrun C., Kieffer I., Testemale D., Delangle P., “d-Penicillamine Tripodal Derivatives as Efficient Copper(I) Chelators”, Inorganic Chemistry  53 (2014) 5229-5239

Alies B., Sasaki I., Proux O., Sayen S., Guillon E., Faller P., Hureau C., “Zn impacts Cu coordination to amyloid-b, the Alzheimer’s peptide, but not the ROS production and the associated cell toxicity”, Chemical Communications 49 (2013) 1214-1216

Jullien A.-S., Gateau C., Kieffer I., Testemale D., Delangle P., “X-Ray Absorption Spectroscopy Proves the Trigonal Planar Sulfur-Only Coordination of Cu(I) with High Affinity Tripodal Pseudopeptides”, Inorganic Chemistry 52 (2013) 9954–9961

D'Angelo P., Della Longa S., Arcovito A., Mancini G., Zitolo A., Chillemi G., Giachin G., Legname G., Benetti F., “Effects of the pathological Q212P mutation on human prion protein non-octarepeat copper binding site”, Biochemistry 51 (2012) 6068–6079

Stellato F., Spevacek A., Proux O., Minicozzi V., Millhauser G., Morante S., “Zinc ions modulate the Cu coordination mode in Prion protein octa-repeat subdomains”, European Biophysics Journal40 (2011) 1259-1270

Benetti F., Ventura M., Salmini B., Ceola S., Carbonera D., Mammi S., Zitolo A., D’Angelo P., Urso E., Maffia M., Salvato B., Spisni E., "Cuprizone neurotoxicity, copper deficiency and neurodegeneration”, NeuroToxicology 31 (2010) 509–517

Petit-Hærtlein I., Girard E., Sarret G., Hazemann J.-L., Gourhant P., Kahn R., Coves J., “Evidence for conformational changes upon copper binding to Cupriavidus metallidurans CzcE”, Biochemistry 49 (2010) 1913–1922

Sarret G., Favier A., Covès J., Hazemann J.-L., Mergeay M., Bersch B. “CopK from Cupriavidus metallidurans CH34 Binds Cu(I) in a Tetrathioether Site: Characterization by X-ray Absorption and NMR Spectroscopy”, Journal of the American Chemical Society 132 (2010) 3770–3777

Poger D., Fillaux C., Miras R., Crouzy S., Delangle P., Mintz E., Den Auwer C., Ferrand M., “Interplay between glutathione, Atx1 and copper: X-ray absorption spectroscopy determination of Cu(I) environment in an Atx1 dimer”, Journal of Biological Inorganic Chemistry 13 (2008) 1239-1248

D’Angelo P., Pacello F., Mancini G., Proux O., Hazemann J.-L., Desideri A., Battistoni A., “X-ray absorption investigation of a unique protein domain able to bind both Cu(I) and Cu(II) at adjacent sites of the N-terminus of Haemophilus ducreyi Cu,Zn superoxide dismutase”, Biochemistry 44 (2005) 13144-13150